Stadium: Court 10 Round: 62 Ground: Clay
| ITF - M25 Hammamet | 2024/02/04 08:00 | Martinez Arjona, Samuel v Giovanni Agostinetto | 6-2,6-2 |
| ITF M25 Madrid | 2023/11/27 11:00 | David Naharro v Martinez Arjona, Samuel | 6-4,0-6,10-5 |
| ITF M25 Madrid | 2023/11/26 13:30 | Martinez Arjona, Samuel v Enrique Bogo | 7-6,6-4 |
| ITF M15 Alcala De Henares | 2023/11/20 11:30 | Martins Rocens v Martinez Arjona, Samuel | 6-2,6-0 |
| ITF M15 Valencia | 2023/11/12 10:00 | Georgii Kravchenko v Martinez Arjona, Samuel | 6-2,5-7,10-7 |
| ITF M25 Benicarlo | 2023/11/05 14:30 | Pujol Navarro, Bruno v Martinez Arjona, Samuel | 6-4,6-4 |
| Castellon, Singles Qualifying M-ITF-ESP-34A | 2023/10/15 08:30 | Martinez Arjona, Samuel v Stijn Slump | 1-6,3-6 |
| ITF M25 Madrid | 2023/09/10 15:00 | Asier Civera Martinez v Martinez Arjona, Samuel | 2-6,6-1,10-6 |
| ITF - M25 Hammamet | 2024/02/04 08:00 | Ferdinand Kloesters v Daniil Savelev | 6-4,6-4 |
| ITF - M25 Hammamet | 2024/01/29 08:30 | Gheorghita, Tudor Stefan v Ferdinand Kloesters | 2-6,1-6 |
| ITF - M25 Hammamet | 2024/01/28 08:00 | Ferdinand Kloesters v Kelsey Stevenson | 6-4,6-2 |