Face à face
| LOL - Prime League - Summer | 2022/06/09 17:40 | Schalke 04 v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Spring Playoffs | 2022/03/03 16:55 | Schalke 04 v Unicorns of Love SE | 1-3 |
| LOL - Prime League - Spring | 2022/02/22 20:40 | Unicorns of Love SE v Schalke 04 | 0-1 |
| LOL - Prime League - Spring | 2022/01/30 21:15 | Schalke 04 v Unicorns of Love SE | 0-1 |
| LOL - Prime League Winter | 2021/10/28 16:00 | Schalke 04 v Unicorns of Love SE | 2-3 |
| LOL - Prime League - Summer | 2021/07/22 15:55 | Unicorns of Love SE v Schalke 04 | 1-0 |
| LOL - Prime League - Summer | 2021/06/24 18:45 | Schalke 04 v Unicorns of Love SE | 0-1 |
| LOL - Prime League - Spring Playoffs | 2021/03/10 17:00 | Unicorns of Love SE v Schalke 04 | 1-2 |
Home History
| LOL - Prime League - Summer | 2022/06/09 17:40 | Schalke 04 v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Summer | 2022/06/07 16:40 | SK Gaming v Schalke 04 | 0-1 |
| LOL - Prime League - Summer | 2022/06/02 18:30 | Schalke 04 v Wave Esports | 1-0 |
| LOL - Prime League - Summer | 2022/05/31 18:50 | PENTA 1860 v Schalke 04 | 0-1 |
| LOL - Prime League - Spring Playoffs | 2022/03/03 16:55 | Schalke 04 v Unicorns of Love SE | 1-3 |
| LOL - Prime League - Spring | 2022/02/24 19:00 | Schalke 04 v GamerLegion | 1-0 |
| LOL - Prime League - Spring | 2022/02/22 20:40 | Unicorns of Love SE v Schalke 04 | 0-1 |
| LOL - Prime League - Spring | 2022/02/20 20:40 | Schalke 04 v BIG | 0-1 |
Away History
| LOL - Prime League - Summer | 2022/06/09 17:40 | Schalke 04 v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Summer | 2022/06/07 18:50 | Unicorns of Love SE v E WIE EINFACH E-SPORTS | 1-0 |
| LOL - Prime League - Summer | 2022/06/02 19:20 | SK Gaming v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Summer | 2022/05/31 17:45 | Unicorns of Love SE v Eintracht Spandau | 0-1 |
| European Masters, Spring Playoffs | 2022/04/30 15:00 | Karmine Corp v Unicorns of Love SE | 3-1 |
| European Masters, Spring Playoffs | 2022/04/21 19:15 | LDLC OL v Unicorns of Love SE | 1-0 |
| European Masters, Spring Playoffs | 2022/04/21 17:20 | Unicorns of Love SE v BISONS Eclub | 1-0 |
| European Masters, Spring Playoffs | 2022/04/21 15:35 | Atleta v Unicorns of Love SE | 0-1 |