Stadium: Court 4 Round: 25 Ground: Hardcourt outdoor
| ITF W25 Monastir | 2022/01/23 11:30 | Hong Yi Cody Wong v Orlova, Natalia | 7-6,6-2 |
| ITF - W15 Monastir | 2021/12/30 08:30 | Ksenia Laskutova v Orlova, Natalia | 6-0,6-2 |
| ITF - W15 Monastir | 2021/12/29 09:40 | Orlova, Natalia v Victoria Muntean | 7-6,5-7,6-1 |
| ITF - W15 Monastir | 2021/12/22 13:00 | Praefke, Pia v Orlova, Natalia | 6-3,6-1 |
| ITF - W15 Monastir | 2021/11/03 09:55 | Julia Middendorf v Orlova, Natalia | 6-4,6-4 |
| ITF - W15 Monastir | 2021/10/27 13:45 | Orlova, Natalia v Kalva, Bhuvana | 6-3,6-4 |
| ITF - W15 Monastir | 2021/10/06 11:40 | Orlova, Natalia v Chiraz Bechri | 0-6,2-6 |
| ITF - W15 Monastir | 2021/09/29 13:00 | Yexin Ma v Orlova, Natalia | 6-2,6-0 |
| ITF W25 Monastir | 2022/01/26 16:25 | Poznikhirenko, Ganna v Sebastianna Scilipoti | 6-2,6-3 |
| UTR Pro Tennis Series Barcelona Women | 2022/01/22 11:00 | Sebastianna Scilipoti v Carrillo Marin, Alba | 1-6,6-2,3-6 |
| UTR Pro Tennis Series Barcelona Women | 2022/01/21 13:00 | Sebastianna Scilipoti v Sevil Yuldasheva | 7-5,6-2 |
| UTR Pro Tennis Series Barcelona Women | 2022/01/19 13:00 | Sebastianna Scilipoti v Celine Simunyu | 6-3,6-4 |
| UTR Pro Tennis Series Barcelona Women | 2022/01/18 10:00 | Sebastianna Scilipoti v Ciobanu, Daniela | 6-2,5-2 |
| UTR Pro Tennis Series Barcelona Women | 2022/01/17 11:30 | Valeria Koussenkova v Sebastianna Scilipoti | 5-7,4-6 |
| UTR Pro Tennis Series Barcelona Women | 2021/12/11 08:00 | Francesca Curmi v Sebastianna Scilipoti | 3-6,6-2,6-0 |
| UTR Pro Tennis Series Barcelona Women | 2021/12/09 12:30 | Sebastianna Scilipoti v Lucinda Gatsiounis | 6-0,5-1 |