Face à face
| LOL - Prime League Winter | 2021/10/28 16:00 | Schalke 04 v Unicorns of Love SE | 2-3 |
| LOL - Prime League - Summer | 2021/07/22 15:55 | Unicorns of Love SE v Schalke 04 | 1-0 |
| LOL - Prime League - Summer | 2021/06/24 18:45 | Schalke 04 v Unicorns of Love SE | 0-1 |
| LOL - Prime League - Spring Playoffs | 2021/03/10 17:00 | Unicorns of Love SE v Schalke 04 | 1-2 |
| LOL - Prime League - Spring | 2021/02/16 17:00 | Schalke 04 v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Spring | 2021/01/20 19:00 | Unicorns of Love SE v Schalke 04 | 1-0 |
| LOL - Prime League Grand Finals | 2020/10/26 17:00 | Schalke 04 v Unicorns of Love SE | 3-1 |
| LOL - Prime League - Summer | 2020/07/14 19:00 | Unicorns of Love SE v Schalke 04 | 0-1 |
Home History
| LOL - Prime League - Spring | 2022/01/27 18:55 | BIG v Schalke 04 | 1-0 |
| LOL - Prime League - Spring | 2022/01/25 17:30 | Schalke 04 v Eintracht Spandau | 0-1 |
| LOL - Prime League - Spring | 2022/01/23 20:00 | PENTA 1860 v Schalke 04 | 1-0 |
| LOL - Prime League - Spring | 2022/01/20 17:40 | Wave Esports v Schalke 04 | 0-1 |
| LOL - Prime League - Spring | 2022/01/18 16:50 | Schalke 04 v MOUZ | 1-0 |
| LOL - Prime League - Spring | 2022/01/13 20:15 | E WIE EINFACH E-SPORTS v Schalke 04 | 0-1 |
| LOL - Prime League - Spring | 2022/01/11 20:10 | Schalke 04 v SK Gaming | 1-0 |
| LOL - Prime League Winter | 2021/11/03 17:00 | Schalke 04 v MOUZ | 1-3 |
Away History
| LOL - Prime League - Spring | 2022/01/27 20:55 | Unicorns of Love SE v Wave Esports | 1-0 |
| LOL - Prime League - Spring | 2022/01/25 18:40 | MOUZ v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Spring | 2022/01/23 16:50 | Unicorns of Love SE v E WIE EINFACH E-SPORTS | 1-0 |
| LOL - Prime League - Spring | 2022/01/20 20:00 | SK Gaming v Unicorns of Love SE | 1-0 |
| LOL - Prime League - Spring | 2022/01/18 19:50 | Unicorns of Love SE v GamerLegion | 0-1 |
| LOL - Prime League - Spring | 2022/01/13 21:25 | Unicorns of Love SE v PENTA 1860 | 1-0 |
| LOL - Prime League - Spring | 2022/01/11 21:50 | BIG v Unicorns of Love SE | 0-1 |
| LOL - Prime League Winter | 2021/11/14 17:00 | Unicorns of Love SE v MOUZ | 1-3 |