Ground: Clay
| ITF Italy F21 | 2014/06/30 12:00 | Pedro Sakamoto v Picco, Francesco | 6-7,4-6 |
| ITF Italy F19 | 2014/06/19 11:55 | Fortuna, Claudio v Picco, Francesco | 5-7,6-4,7-5 |
| ITF Italy F19 | 2014/06/17 12:25 | Basso, Andrea v Picco, Francesco | 7-6,2-6,2-6 |
| ITF Egypt F33 | 2014/06/13 14:00 | Picco, Francesco v Zhurbin, Alexander | 4-6,4-6 |
| ITF Egypt F33 | 2014/06/12 15:15 | Picco, Francesco v Igoshin, Alexander | 6-4,6-3 |
| ITF Egypt F33 | 2014/06/10 16:15 | Picco, Francesco v Vervoort, Mark | 6-1,6-4 |
| ITF Italy F15 | 2014/05/21 09:30 | Daniel Dutra Da Silva v Picco, Francesco | 6-7,6-4,6-0 |
| ITF Italy F15 | 2014/05/19 14:10 | Picco, Francesco v Pedro Sakamoto | 6-4,1-6,6-1 |
| ITF Romania F7 | 2014/07/06 11:00 | Cornea, Vlad Victor v Patrui, Andrei | 6-3,6-1 |
| ITF Romania F4 | 2014/06/15 08:00 | Cornea, Vlad Victor v Botezan, George | 6-2,6-1 |
| ITF Romania F3 | 2014/05/26 07:00 | Souto, David v Cornea, Vlad Victor | 6-3,2-6,6-2 |
| ITF Romania F2 | 2014/05/21 07:00 | Cornea, Vlad Victor v Antonescu, Vasile | 1-6,3-6 |