| Challenge Plus Portugal Open 2020, WS, Quali | 2020/02/14 12:35 | Aikaterini Toliou v Orawan Paranang | L | 0-4 |
| ITTF Challenge, Polish Open 2019, WS, Group Stage | 2019/10/16 13:55 | Aikaterini Toliou v Xunyao Shi | L | 1-3 |
| Euro Team Champs Women | 2019/09/04 15:30 | Gasnier, Laura v Aikaterini Toliou | L | 3-0 |
| Euro Team Champs Women | 2019/09/04 14:30 | Stephanie Loeuillette v Aikaterini Toliou | W | 1-3 |
| Euro Team Champs Women | 2019/09/03 09:30 | Aikaterini Toliou v Sarah De Nutte | L | 1-3 |
| Euro Team Champs Women | 2019/09/03 08:00 | Xia Lian Ni v Aikaterini Toliou | L | 3-0 |
| European Games Women | 2019/06/22 12:00 | Jieni Shao v Aikaterini Toliou | L | 4-2 |
| ITTF European Team Championships, Women Singles | 2019/05/19 09:10 | Barbora Balazova v Aikaterini Toliou | L | 3-0 |
| Europe Cup - Femmes | 2020/02/15 18:41 | Szabina Surjan v Fetukhina, Margarita | L | 1-3 |