[10] Williams, Serena 7-5,6-4 Ekaterina Alexandrova [48] 2019-08-08 23:00
Stadium: Centre Court Round: 26 Ground: Hardcourt outdoor
Home History
| WTA Toronto | 2019/08/07 23:05 | Williams, Serena v Elise Mertens | 6-3,6-3 |
| Wimbledon Women | 2019/07/13 13:00 | Williams, Serena v Simona Halep | 2-6,2-6 |
| Wimbledon Women | 2019/07/11 13:30 | Williams, Serena v Srtycova, Barbora | 6-1,6-2 |
| Wimbledon Women | 2019/07/09 12:00 | Alison Riske v Williams, Serena | 4-6,6-4,3-6 |
| Wimbledon Women | 2019/07/08 12:00 | Williams, Serena v Suarez Navarro, Carla | 6-2,6-2 |
| Wimbledon Women | 2019/07/06 12:00 | Williams, Serena v Goerges, Julia | 6-3,6-4 |
| Wimbledon Women | 2019/07/04 15:40 | Williams, Serena v Kaja Juvan | 2-6,6-2,6-4 |
| Wimbledon Women | 2019/07/02 15:45 | Williams, Serena v Gatto-Monticone, Giulia | 6-2,7-5 |
Away History
| WTA Toronto | 2019/08/07 19:40 | Ekaterina Alexandrova v Shuai Zhang | 6-4,6-3 |
| WTA Toronto | 2019/08/06 15:00 | Doi, Misaki v Ekaterina Alexandrova | 2-6,2-6 |
| WTA Toronto | 2019/08/04 15:50 | Ekaterina Alexandrova v Timea Babos | 7-5,7-6 |
| WTA Toronto | 2019/08/03 15:50 | Ekaterina Alexandrova v Louise Kwong | 6-0,6-1 |
| WTA San Jose | 2019/07/30 00:15 | Ekaterina Alexandrova v Maria Sakkari | 1-6,4-6 |
| Wimbledon Women | 2019/07/02 10:00 | Ekaterina Alexandrova v Katerina Siniakova | 6-2,1-6,1-6 |
| WTA Eastbourne | 2019/06/27 16:00 | Ekaterina Alexandrova v Karolina Pliskova | 2-6,0-6 |
| WTA Eastbourne | 2019/06/25 17:00 | Ekaterina Alexandrova v Bencic, Belinda | 6-7,6-2,6-3 |