[10] Williams, Serena 6-3,6-3 Elise Mertens [20] 2019-08-07 23:05
Stadium: Centre Court Round: 25 Ground: Hardcourt outdoor
Home History
| Wimbledon Women | 2019/07/13 13:00 | Williams, Serena v Simona Halep | 2-6,2-6 |
| Wimbledon Women | 2019/07/11 13:30 | Williams, Serena v Srtycova, Barbora | 6-1,6-2 |
| Wimbledon Women | 2019/07/09 12:00 | Alison Riske v Williams, Serena | 4-6,6-4,3-6 |
| Wimbledon Women | 2019/07/08 12:00 | Williams, Serena v Suarez Navarro, Carla | 6-2,6-2 |
| Wimbledon Women | 2019/07/06 12:00 | Williams, Serena v Goerges, Julia | 6-3,6-4 |
| Wimbledon Women | 2019/07/04 15:40 | Williams, Serena v Kaja Juvan | 2-6,6-2,6-4 |
| Wimbledon Women | 2019/07/02 15:45 | Williams, Serena v Gatto-Monticone, Giulia | 6-2,7-5 |
| Open de France - Femmes | 2019/06/01 16:30 | Williams, Serena v Sofia Kenin | 2-6,5-7 |
Away History
| WTA Toronto | 2019/08/05 15:00 | Elise Mertens v Aliaksandra Sasnovich | 3-6,6-3,6-1 |
| WTA San Jose | 2019/08/01 19:20 | Ahn, Kristie v Elise Mertens | 6-3,6-3 |
| Wimbledon Women | 2019/07/08 10:00 | Srtycova, Barbora v Elise Mertens | 4-6,7-5,6-2 |
| Wimbledon Women | 2019/07/06 10:00 | Elise Mertens v Qiang Wang | 6-2,6-7,6-4 |
| Wimbledon Women | 2019/07/04 12:30 | Elise Mertens v Niculescu, Monica | 7-5,6-0 |
| Wimbledon Women | 2019/07/02 10:00 | Elise Mertens v Fiona Ferro | 6-2,6-0 |
| WTA Eastbourne | 2019/06/26 12:35 | Elise Mertens v Karolina Pliskova | 1-6,2-6 |
| WTA Eastbourne | 2019/06/25 12:50 | Marketa Vondrousova v Elise Mertens | 1-6,7-5,2-6 |